Fayalite R070293

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Record 5 of 8  


Name: Fayalite
RRUFF ID: R070293
Ideal Chemistry: Fe2+2(SiO4)
Locality: Pike's Peak, Teller County, Colorado, USA
Source: Michael Scott S106013 [view label]
Owner: RRUFF
Description: Black single crystal fragment with internal hints of red and green
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Olivine (61) ]
Quick search: [ All Fayalite samples (8) ]
CHEMISTRY 
RRUFF ID: R070293.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Fe2+1.87Mn2+0.13)Σ=2Si1.00O4 ; trace amounts of Mg
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented and mounted on a pin.
Pin ID: L01546
Orientation: Laser parallel to  c*  (0 0 1).     Fiducial mark perpendicular to laser is parallel to  a   [1 0 0].
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  orientation angle.

Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070293
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R070293.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R070293.1
Sample Description: Powder
Cell Refinement Output: a: 4.8245(6)Å    b: 10.4959(4)Å    c: 6.0974(4)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 308.75(3)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Fayalite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Gmelin C G (1840) Chemische Untersuchung des Fayalits, Annalen der Physik und Chemie, 51, 160-164   [view file]

Gmelin C G (1840) Chemische untersuchung des Fayalits, eines neuen Minerals von der Azorischen Insel Fayal (Chemical analysis of fayalite, a new mineral from the Azores island of Fayal), Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefakten-Kunde, 1840, 596-597   [view file]

Wheeler E P (1965) Fayalitic olivine in northern Newfoundland-Labrador, The Canadian Mineralogist, 8, 339-346   [view file]

Fisher G W (1967) Fe-Mg olivine solid solutions, Carnegie Institution of Washington Year book, 66, 209-217

Birle J D, Gibbs G V, Moore P B, Smith J V (1968) Crystal structures of natural olivines, American Mineralogist, 53, 807-824   [view file]

Louisnathan S J, Smith J V (1968) Cell dimensions of olivine, Mineralogical Magazine, 36, 1123-1134   [view file]

Wyderko M, Mazanek E (1968) The mineralogical characteristics of calcium-iron olivines, Mineralogical Magazine, 36, 955-961   [view file]

Fisher G W, Medaris L G (1969) Cell dimensions and X-ray determinative curve for synthetic Mg-Fe olivines, American Mineralogist, 54, 741-753   [view file]

Burns R G, Huggins F E (1972) Cation determinative curves for Mg-Fe-Mn olivines from vibrational spectra, American Mineralogist, 57, 967-985   [view file]

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Smyth J R (1975) High temperature crystal chemistry of fayalite, American Mineralogist, 60, 1092-1097   [view file]

Mokeeva V I, Simonov M A, Belokoneva E L, Makarov E S, Ivanov V I, Rannev N V (1976) X-ray study of details of structure and distribution of magnesium and iron atoms in lunar and terrestrial olivines, Akademii Nauk SSSR, Eksperimental’no-Metodicheskie Issledovaniya Rudnykh Mineralov, Moscow, 13, 84-92

Mossman D J, Pawson D J (1976) X-ray and optical characterization of the forsterite-fayalite-tephroite series with comments on knebelite from Bluebell mine, British Columbia, The Canadian Mineralogist, 14, 479-486   [view file]

Bayliss P (1977) X-ray and optical characterization of the forsterite-fayalite-tephroite series with comments on knebelite from Bluebell Mine, Britich Columbia: discussion, The Canadian Mineralogist, 15, 267-267   [view file]

Hazen R M (1977) Effects of temperature and pressure on the crystal structure of ferromagnesian olivine, American Mineralogist, 62, 286-295   [view file]

Schwab R G, Küstner D (1977) Präzisionsgitterkonstantenbestimmung zur Festlegung röntgenographischer Bestimmungskurven für synthetische Olivine der Mischkristallreihe Forsterit-Fayalit, Neues Jahrbuch für Mineralogie, Monatshefte, 5, 205-215

Riekel C, Weiss A (1978) Cation-ordering in synthetic Mg2-xFexSiO4-olivines, Zeitschrift für Naturforschung B Anorganische Chemie, Organische Chemie, 33b, 731-736

Takei H (1978) Growth of fayalite (Fe2SiO4) single crystals by the floating-zone method, Journal of Crystal Growth, 43, 463-468

Fujino K, Sasaki S, Takéuchi Y, Sadanaga R (1981) X-ray determination of electron distributions in forsterite, fayalite and tephroite, Acta Crystallographica, B37, 513-518

Suzuki I, Seya K, Takei H, Sumino Y (1981) Thermal expansion of fayalite Fe2SiO4, Physics and Chemistry of Minerals, 7, 60-63

Annersten H, Ericsson T, Filippidis A (1982) Cation ordering in Ni-Fe olivines, American Mineralogist, 67, 1212-1217   [view file]

Nord A G, Annersten H, Filippidis A (1982) The cation distribution in synthetic Mg-Fe-Ni olivines, American Mineralogist, 67, 1206-1211   [view file]

Annersten H, Adetunji J, Filippidis A (1984) Cation ordering in Fe-Mn silicate olivines, American Mineralogist, 69, 1110-1115   [view file]

Annersten H, Filippidis A (1984) Cation ordering in Ni-Fe olivines: reply, American Mineralogist, 69, 164-164   [view file]

Ike E C, Bowden P, Martin R F (1984) Fayalite and clinopyroxene in the porphyries of the Tibchi anorogenic ring-complex, Nigeria: postmagmatic initiation of a peralkaline trend, The Canadian Mineralogist, 22, 401-409   [view file]

Takéuchi Y, Yamanaka T, Haga N, Hirano M (1984) High-temperature crystallography of olivines and spinels, in Materials Science of the Earth's Interior Terra Scientific Pub. Co. Tokyo 191-231

Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe2SiO4 and rutile, TiO2 under high pressure, Physica B, 139, 333-336

Ballet O, Fuess H, Fritzsche T (1987) Magnetic structure and cation distribution in (Fe,Mn)2SiO4 (olivine) by neutron diffraction, Physics and Chemistry of Minerals, 15, 54-58

Boström D (1987) Single-crystal X-ray diffraction studies of synthetic Ni-Mg olivine solid solutions, American Mineralogist, 72, 965-972   [view file]

McCormick T C, Smyth J R, Lofgren G E (1987) Site occupancies of minor elements in synthetic olivines as determined by channeling-enhanced X-ray emission, Physics and Chemistry of Minerals, 14, 368-372

Motoyama T, Matsumoto T (1989) The crystal structures and the cation distributions of Mg and Fe of natural olivines, Mineralogical Journal, 14, 338-350

Chopelas A (1991) Single crystal Raman spectra of forsterite, fayalite, and monticellite, American Mineralogist, 76, 1101-1109   [view file]

Akamatsu T, Kumazawa M, Aikawa N, Takei H (1993) Pressure effect on the divalent cation distribution in nonideal solid solution of forsterite and fayalite, Physics and Chemistry of Minerals, 19, 431-444

Kolesov B A, Tanskaya J V (1996) Raman spectra and cation distribution in the lattice of olivines, Materials Research Bulletin, 31, 1035-1044   [link]

Müller-Sommer M, Hock R, Kirfel A (1997) Rietveld refinement study of the cation distribution in (Co, Mg)-olivine solid solution, Physics and Chemistry of Minerals, 24, 17-23

Pani E, Rizzo R, Raudsepp M (1997) Manganoan-fayalite-bearing granitic pegmatite from Quirra, Sardinia: relation to host plutonic rocks and tectonic affiliation, The Canadian Mineralogist, 35, 119-133   [view file]

Rasmussen M G, Evans B W, Kuehner S M (1998) Low–temperature fayalite, greenalite, and minnesotaite from the Overlook gold deposit, Washington: phase relations in the system FeO–SiO2–H2O, The Canadian Mineralogist, 36, 147-162   [view file]

Redfern S A T, Knight K S, Henderson C M B, Wood B J (1998) Fe-Mn cation ordering in fayalite-tephroite (FexMn1-X)2SiO4 olivines: a neutron diffraction study, Mineralogical Magazine, 62, 607-615   [view file]

Zhang L (1998) Single crystal hydrostatic compression of (Mg,Mn,Fe,Co)2SiO4 olivines, Physics and Chemistry of Minerals, 25, 308-312

Ovchinnikov N O, Nikitina L P (1999) The real structure and thermodynamic properties of olivine solid solutions (FexMn1-x)2SiO4, Doklady Akademii Nauk, 368, 535-539

Merli M, Oberti R, Caucia F, Ungaretti L (2001) Determination of site population in olivine: Warnings on X-ray data treatment refinement, American Mineralogist, 86, 55-65   [view file]

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Speziale S, Duffy T S, Angel R J (2004) Single-crystal elasticity of fayalite to 12 GPa, Journal of Geophysical Research, 109, 1-15

Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006   [link]

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Nestola F, Pasqual D, Smyth J, Novella D, Secco L, Manghnani M, Negro A D, (2011) New accurate elastic parameters for the forsterite-fayalite solid solution, American Mineralogist, 96, 1742-1747

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Kroll H, Kirfel A, Heinemann R (2014) Axial thermal expansion and related thermophysical parameters in the Mg,Fe olivine solid-solution series, European Journal of Mineralogy, 26, 607-621

Xu H, Shen Z, Konishi H, Fu P, Szlufarska I (2014) Crystal structures of laihunite and intermediate phases between laihunite-1M and fayalite: Z-contrast imaging and ab initio study, American Mineralogist, 99, 881-889

Burnley P C (2015) Elastic plastic self-consistent (EPSC) modeling of plastic deformation in fayalite olivine, American Mineralogist, 100, 1424-1433

Martin A M, Médard E, Devouard B, Keller L P, Righter K, Devidal J L, Rahman Z (2015) Fayalite oxidation processes in Obsidian Cliffs rhyolite flow, Oregon, American Mineralogist, 100, 1153-1164

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Zhang J S, Hu Y, Shelton H, Kung J, Dera P (2017) Single-crystal X-ray diffraction study of Fe2SiO4 fayalite up to 31 GPa, Physics and Chemistry of Minerals, 44, 171-179

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Geiger C A, Vielreicher N M, Dachs E (2021) Are the thermodynamic properties of natural and synthetic Mg2SiO4-Fe2SiO4 olivines the same?, American Mineralogist, 106, 317-321

Liu D, Guo X, Smyth J R, Wang X, Zhu X, Miao Y, Bai J, Ye Y (2021) High-temperature and high-pressure Raman spectra of Fo89Fa11 and Fo58Fa42 olivines: Iron effect on thermodynamic properties, American Mineralogist, 106, 1668-1678